Mechanism of the cooperative Si–H bond activation at Ru–S bonds† †Electronic supplementary information (ESI) available: Experimental procedures and computational details, characterization, crystallographic and quantum-chemical calculation data as well as NMR spectra. CCDC 1055362–1055364. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc01035g

Gold(iii)–arene complexes by insertion of olefins into gold–aryl bonds† †Electronic supplementary information (ESI) available: Experimental details (syntheses, analytical data and copies of 1H, 13C and 31P NMR spectra), crystallographic data of 2 and computational details. CCDC 1526613 and 1538015. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc00145b Click here for additional data file. Click here for additional data file.

Formation of a C–C double bond from two aliphatic carbons. Multiple C–H activations in an iridium pincer complex† †Electronic supplementary information (ESI) available: Experimental details, characterization data, Cartesian coordinates, additional graphs and computational details. CCDC 1024127–1024129. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4sc03839h Click here for additional data file. Click here for additional data file.

Highly enantioselective access to diketopiperazines via cinchona alkaloid catalyzed Michael additions† †Electronic supplementary information (ESI) available: Experimental procedures, analytical data and NMR spectra, X-ray data. CCDC 977363, 977364, 977365 and 1017592. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4sc03218g

A nitrogen-base catalyzed generation of organotin(ii) hydride from an organotin trihydride under reductive dihydrogen elimination† †Electronic supplementary information (ESI) available: Detailed information concerning the general synthetic procedures, NMR spectroscopy and crystallographic details. Detailed explanations on the kinetic measurements and selected 1D NMR spectra as well as details on the computational considerations. CCDC 1061347–1061349. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc01561h Click here for additional data file. Click here for additional data file.

Institut für Anorganische Chemie, Auf Germany. E-mail: lars.wesemann@uni-tueb School of Chemistry, Monash University, PO Institut für Organische Chemie, Auf der Mo † Electronic supplementary information concerning the general synthetic p crystallographic details. Detailed explanat selected 1D NMR spectra as well considerations. CCDC 1061347–1061349. CIF or other electronic format see DOI: 10 Ci...

A thiocyanopalladation/carbocyclization transformation identified through enzymatic screening: stereocontrolled tandem C–SCN and C–C bond formation† †Electronic supplementary information (ESI) available: Enzymatic screening procedures, detailed synthetic procedures and compilations of spectroscopic data, as well as copies of NMR spectra for new compounds. CCDC 1513686 and 1513687. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc04083k